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By employing 2-( p-fluorophenyl)-1H-imidazole-4,5-dicarboxylic acid( p-FPh H_3IDC) and2,2'-bipy,to react with cadmium( Ⅱ) ion,a new supramolecule [Cd( p-FPh H_2IDC)2( 2,2'-bipy) ]( complex 1) was successfully synthesized. Complex 1 was characterized by elemental analysis,IR spectroscopy and single crystal X-ray diffraction. In complex 1,the [Cd( p-FPh H_2IDC)2( 2,2'-bipy) ]units were joined through intermolecular hydrogen bonds to form a 1D chain. Then the 2D sheets were formed by π-π interactions between the chains. Finally,these sheets were piled up into a 3D solid-state structure by the strong intermolecular interactions. Complex 1 indicated good thermal stability below 345. 5 ℃.
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Basic Information:
DOI：10.13705/j.issn.1671-6841.2016048
China Classification Code:O641.4
Citation Information:
[1]LIU Ailing,JIAO Yanbin,WANG Qi ,et al.Synthesis,Crystal Structure and Thermal Properties of a 3D Cd(Ⅱ) Supramolecule Complex[J].Journal of Zhengzhou University(Natural Science Edition),2016,48(03):99-102.DOI:10.13705/j.issn.1671-6841.2016048.
Fund Information:
国家自然科学基金资助项目(J1210060)
2016-10-17
2016-10-17
2016-10-17